explain qualitatively, in terms both of the Boltzmann distribution and of frequency of effective collisions, the effect of temperature change on the rate of a reaction

explain and use the terms catalyst and catalysis: (a) explain that, in the presence of a catalyst, a reaction has a different mechanism, i.e. one of lower activation energy (b) explain this catalytic effect in terms of the Boltzmann distribution (c) construct and interpret a reaction pathway diagram, for a reaction in the presence and absence of an effective catalyst