describe geometrical (cis/trans) isomerism in alkenes, and explain its origin in terms of restricted rotation due to the presence of π bonds
recall the reactions (reagents and conditions) by which alkanes can be produced: (a) addition of hydrogen to an alkene in a hydrogenation reaction, \( H_2(g) \) and Pt/Ni catalyst and heat (b) cracking of a longer chain alkane, heat with \( Al_2O_3 \)
describe the following reactions of alkenes: (a) the electrophilic addition of (i) hydrogen in a hydrogenation reaction, \( H_2(g) \) and Pt/Ni catalyst and heat (ii) steam, \( H_2O(g) \) and \( H_3PO_4 \) catalyst (iii) a hydrogen halide, \( HX(g) \), at room temperature (iv) a halogen, \( X_2 \) (b) the oxidation by cold dilute acidified \( KMnO_4 \) to form the diol (c) the oxidation by hot concentrated acidified \( KMnO_4 \) leading to the rupture of the carbon–carbon double bond and the identities of the subsequent products to determine the position of alkene linkages in larger molecules (d) addition polymerisation exemplified by the reactions of ethene and propene