Older MCQs might not have the typical A, B, C,
D
choices. They
have choices 1, 2, 3, and a combination of them is the answer. Below is the key that maps such
combinations to the answer.
A
1, 2 and 3 are correct
B
1 and 2 only are correct
C
2 and 3 only are correct
D
1 only is correct
recall the reactions by which carboxylic acids can be produced: (a) oxidation of primary alcohols and aldehydes with acidified \( K_2Cr_2O_7 \) or acidified \( KMnO_4 \) and refluxing (b) hydrolysis of nitriles with dilute acid or dilute alkali followed by acidification (c) hydrolysis of esters with dilute acid or dilute alkali and heat followed by acidification
recall the reactions (reagents and conditions) by which aldehydes and ketones can be produced: (a) the oxidation of primary alcohols using acidified \( K_2Cr_2O_7 \) or acidified \( KMnO_4 \) and distillation to produce aldehydes (b) the oxidation of secondary alcohols using acidified \( K_2Cr_2O_7 \) or acidified \( KMnO_4 \) and distillation to produce ketones
deduce the presence of a CH\(_3\)CH(OH)- group in an alcohol, CH\(_3\)CH(OH)-R, from its reaction with alkaline I\(_2\)(aq) to form a yellow precipitate of tri-lodomethane and an ion, \( RCO_2^-\)
