Older MCQs might not have the typical A, B, C,
D
choices. They
have choices 1, 2, 3, and a combination of them is the answer. Below is the key that maps such
combinations to the answer.
A
1, 2 and 3 are correct
B
1 and 2 only are correct
C
2 and 3 only are correct
D
1 only is correct
recall the reactions (reagents and conditions) by which aldehydes and ketones can be produced: (a) the oxidation of primary alcohols using acidified \( K_2Cr_2O_7 \) or acidified \( KMnO_4 \) and distillation to produce aldehydes (b) the oxidation of secondary alcohols using acidified \( K_2Cr_2O_7 \) or acidified \( KMnO_4 \) and distillation to produce ketones
describe the following reactions of alkenes: (a) the electrophilic addition of (i) hydrogen in a hydrogenation reaction, \( H_2(g) \) and Pt/Ni catalyst and heat (ii) steam, \( H_2O(g) \) and \( H_3PO_4 \) catalyst (iii) a hydrogen halide, \( HX(g) \), at room temperature (iv) a halogen, \( X_2 \) (b) the oxidation by cold dilute acidified \( KMnO_4 \) to form the diol (c) the oxidation by hot concentrated acidified \( KMnO_4 \) leading to the rupture of the carbon–carbon double bond and the identities of the subsequent products to determine the position of alkene linkages in larger molecules (d) addition polymerisation exemplified by the reactions of ethene and propene
recall the reactions by which carboxylic acids can be produced: (a) oxidation of primary alcohols and aldehydes with acidified \( K_2Cr_2O_7 \) or acidified \( KMnO_4 \) and refluxing (b) hydrolysis of nitriles with dilute acid or dilute alkali followed by acidification (c) hydrolysis of esters with dilute acid or dilute alkali and heat followed by acidification
