9701_s09_qp_4
A paper of Chemistry, 9701
Questions:
9
Year:
2009
Paper:
4
Variant:
0
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1
Explain what is meant by the Bronsted-Lowry theory of acids and bases. The Ka values for some organic acids are listed below. acid Ka /mol dm−3 CH3CO2H 1.7  10−5 Cl CH2CO2H 1.3  10−3 Cl 2CHCO2H 5.0  10−2 Explain the trend in Ka values in terms of the structures of these acids. Calculate the pH of a 0.10 mol dm−3 solution of Cl CH2CO2H. pH = For Examiner’s Use Use the following axes to sketch the titration curve you would obtain when 20 cm3 of 0.10 mol dm−3 NaOH is added gradually to 10 cm3 of 0.10 mol dm−3 Cl CH2CO2H. pH volume of NaOH added / cm Write suitable equations to show how a mixture of ethanoic acid, CH3CO2H, and sodium ethanoate acts as a buffer solution to control the pH when either an acid or an alkali is added. Calculate the pH of a buffer solution containing 0.10 mol dm−3 ethanoic acid and 0.20 mol dm−3 sodium ethanoate. pH =
7. Equilibria  →  7.2. Brønsted–Lowry theory of acids and bases
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For Examiner’s Use Describe the observations you would make when concentrated sulfuric acid is added to separate portions of NaCl and NaBr. Write an equation for each reaction that occurs. NaCl : observation equation NaBr: observation equation By quoting relevant E o- data from the Data Booklet, explain how the observations you have described above relate to the relative oxidising power of the elements. By referring to relevant E o- data choose a suitable reagent to convert Br2 into Br −. Write an equation and calculate the E o- for the reaction.
11. Group 17  →  11.4. The reactions of chlorine
10. Group 2  →  10.1. Similarities and trends in the properties of the Group 2 metals, magnesium to barium, and their compounds
11. Group 17  →  11.2. The chemical properties of the halogen elements and the hydrogen halides
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For Examiner’s Use Explain what is meant by the term transition element. Complete the electronic configuration of the vanadium atom, 1s22s22p6 the Cu2+ ion. 1s22s22p6 List the four most likely oxidation states of vanadium. Describe what you would see, and explain what happens, when dilute aqueous ammonia is added to a solution containing Cu2+ ions, until the ammonia is in an excess. Copper powder dissolves in an acidified solution of sodium vanadate(, NaVO3, to produce a blue solution containing VO2+ and Cu2+ ions. By using suitable half-equations from the Data Booklet, construct a balanced equation for this reaction.
2. Atoms, molecules and stoichiometry  →  2.3. Formulas
11. Group 17  →  11.3. Some reactions of the halide ions
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For Examiner’s Use The reaction between iodide ions and persulfate ions, S2O 8 2−, is slow. 2I− + S2O 8 2− I2 + 2SO 4 2− The reaction can be speeded up by adding a small amount of Fe2+ or Fe3+ ions. The following two reactions then take place. 2I− + 2Fe3+ I2 + 2Fe2+ 2Fe2+ + S2O 8 2− 2Fe3+ + 2SO 4 2− What type of catalysis is occurring here? The rates of reactions 2 and 3 are both faster than that of reaction 1. By considering the species involved in these reactions, suggest a reason for this. The following reaction pathway diagram shows the enthalpy profile of reaction 1. enthalpy progress of reaction Use the same axes to draw the enthalpy profiles of reaction 2 followed by reaction 3, starting reaction 2 at the same enthalpy level as reaction 1. For Examiner’s Use The oxidation of SO2 to SO3 in the atmosphere is speeded up by the presence of nitrogen oxides. Describe the environmental significance of this reaction. Describe a major source of SO2 in the atmosphere. By means of suitable equations, show how nitrogen oxides speed up this reaction.
12. Nitrogen and sulfur  →  12.1. Nitrogen and sulfur
8. Reaction kinetics  →  8.3. Homogeneous and heterogeneous catalysts
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For Examiner’s Use In the following boxes draw the structural formulae of three alcohols having straight (i.e. unbranched) chains, with the molecular formula C5H12O. A B C Use the letters A, B or C as appropriate when answering the following questions. Each letter may be used once, more than once or not at all. Which of the alcohols are chiral? Which of these alcohols react with alkaline aqueous iodine? Describe the observation you would make during this reaction. Draw the structural formulae of the products of this reaction. Draw the structural formula of the product obtained when each of the alcohols A, B and C is heated with an excess of acidified K2Cr2O7. A B C For Examiner’s Use One of the many suggestions for converting biomass into liquid fuel for motor transport is the pyrolysis (i.e. heating in the absence of air) of cellulose waste, followed by the synthesis of alkanes. In the first reaction, cellulose, (C6H10O5)n, is converted into a mixture of carbon monoxide and hydrogen. Some carbon is also produced. Complete and balance the equation for this reaction. (C6H10O5)n ————————— + ————————— + ————————— The second reaction involves the combination of CO and H2 to produce alkanes such as heptane. 7CO + 15H2 C7H16 + 7H2O heptane Using the value of 1080 kJ mol−1 as the value for the CO bond energy in CO, and other relevant bond energies from the Data Booklet, calculate the ∆H for this reaction. ∆H = kJ mol−1
17. Carbonyl compounds  →  17.1. Aldehydes and ketones
14. Hydrocarbons  →  14.2. Alkenes
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For Examiner’s Use Phenol and chlorobenzene are less reactive towards certain reagents than similar non-aromatic compounds. Thus hexan-1-ol can be converted into hexylamine by the following two reactions, I II CH3(CH2)5OH CH3(CH2)5Cl CH3(CH2)5NH2 hexan-1-ol 1-chlorohexane hexylamine whereas neither of the following two reactions takes place. OH Cl NH2 Suggest reagents and conditions for reaction I, , reaction II. . What type of reaction is reaction II? Suggest a reason why chlorobenzene is much less reactive than 1-chlorohexane. For Examiner’s Use Phenylamine can be made from benzene by the following two reactions. NH2 NO2 III IV Suggest reagents and conditions for reaction III, , reaction IV. . State the type of reaction for reaction III, , reaction IV. . Suggest a reagent that could be used to distinguish phenylamine from hexylamine. reagent and conditions observation with phenylamine observation with hexylamine For Examiner’s Use Phenylamine is used to make azo dyes. In the following boxes draw the structural formula of the intermediate D and of the azo dye E. D E NH2 NaNO2 + HCl in NaOHT < 5°C OH CH3 CH3
13. An introduction to AS Level organic chemistry  →  13.2. Characteristic organic reactions
14. Hydrocarbons  →  14.2. Alkenes
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Metals play a vital part in biochemical systems. In this question you need to consider why some metals are essential to life, whilst others are toxic. For each of the metals, state where it might be found in a living organism, and what its chemical role is. iron location in organism role sodium location in organism role zinc location in organism role Heavy metals such as mercury are toxic, and it is important that these do not enter the food chain. Give a possible source of mercury in the environment. Describe and explain two reasons why mercury is toxic, using diagrams and/or equations to help your explanation. [Total : 10]
10. Group 2  →  10.1. Similarities and trends in the properties of the Group 2 metals, magnesium to barium, and their compounds
12. Nitrogen and sulfur  →  12.1. Nitrogen and sulfur
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For Examiner’s Use A large number of organic compounds are soluble in both water and non-aqueous solvents such as hexane. If such a compound is shaken with a mixture of water and the non-aqueous solvent, it will dissolve in both solvents depending on the solubility in each. State what is meant by the term partition coefficient. When 100 cm3 of an aqueous solution containing 0.50 g of an organic compound X was shaken with 20 cm3 of hexane, it was found that 0.40 g of X was extracted into the hexane. Calculate the partition coefficient of X between hexane and water. If two 10 cm3 portions of hexane were used instead of a single 20 cm3 portion, calculate the total amount of X extracted and compare this with the amount extracted using one 20 cm3 portion. For Examiner’s Use PCBs are highly toxic compounds released into the atmosphere when some plastics are burned at insufficiently high temperatures. In recent years PCB residues have been found in the breast milk of Inuit mothers in northern Canada. Foods, such as oily fish, seal and whale meat, which are high in fat, form an important part of the Inuit diet. Suggest why berries and drinking water are not contaminated by PCBs in the same way that oily fish, seal and whale meat are. Based on the information provided, what can you say about the partition coefficient between fat and water for PCB residues? For Examiner’s Use The diagram shows the result of two-way paper chromatography. X starting point solvent 1 solvent How many spots were there after the first solvent had been used? Circle the spot that moved very little in solvent 2, but moved a greater distance in solvent 1. Draw a square around the spot that could be separated from the rest by using only solvent 1.
11. Group 17  →  11.4. The reactions of chlorine
2. Atoms, molecules and stoichiometry  →  2.3. Formulas
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For Examiner’s Use Spider silk is a natural polymer which has an exceptional strength for its weight. Kevlar is a man-made polymer designed to have similar properties. It has a wide variety of uses from sporting equipment to bullet-proof vests. C O H N H N O C N H C O O C N H O C Kevlar In Kevlar, the polymer strands line up to form strong sheets with bonds between the strands. On the diagram above, draw part of a second polymer chain showing how bonds could be formed between the chains. Suggest what type of bonds these are. Draw two possible monomer molecules for making the polymer Kevlar. The transport of oil by sea has resulted in a number of oil spills in recent years. As well as a waste of a valuable resource, these have caused major environmental problems. Traditional sorbent materials absorb water and sink. Researchers have developed new sorbent materials to help collect the spilled oil. The sorbent consists of a material called ‘hydrophobic aerogels’. This is a network of silicon(oxide with some of the silicon atoms attached to fluorine-containing groups. —O—Si—CH2—CF3 The introduction of these fluorine-containing groups allows the oil to be absorbed but not the water. Tests show that these materials can absorb more than 200 times their mass of oil without sinking. Suggest what the word hydrophobic means. Suggest why the fluorine-containing groups allow oil to pass through but not water molecules. Suggest another important fluorine-containing polymer that repels water-containing materials.
20. Polymerisation  →  20.1. Addition polymerisation
14. Hydrocarbons  →  14.2. Alkenes
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