state and explain the shapes of, and bond angles in, molecules by using VSEPR theory, including as simple examples: • BF\(_3\) (trigonal planar, 120°) • CO\(_2\) (linear, 180°) • CH\(_4\) (tetrahedral, 109.5°) • NH\(_3\) (pyramidal, 107°) • H\(_2\)O (non-linear, 104.5°) • SF\(_6\) (octahedral, 90°) • PF\(_5\) (trigonal bipyramidal, 120° and 90°)
define covalent bonding as electrostatic attraction between the nuclei of two atoms and a shared pair of electrons (a) describe covalent bonding in molecules including: - hydrogen, H\(_2\) - oxygen, O\(_2\) - nitrogen, N\(_2\) - chlorine, Cl\(_2\) - hydrogen chloride, HCl - carbon dioxide, CO\(_2\) - ammonia, NH\(_3\) - methane, CH\(_4\) - ethane, C\(_2\)H\(_6\) - ethene, C\(_2\)H\(_4\) (b) understand that elements in period 3 can expand their octet including in the compounds sulfur dioxide, SO\(_2\), phosphorus pentachloride, PCl\(_5\), and sulfur hexafluoride, SF\(_6\) (c) describe coordinate (dative covalent) bonding, including in the reaction between ammonia and hydrogen chloride gases to form the ammonium ion, NH\(_4^+\), and in the Al\(_2\)Cl\(_6\) molecule
describe and explain: (a) the basicity of ammonia, using the Brønsted–Lowry theory (b) the structure of the ammonium ion and its formation by an acid–base reaction (c) the displacement of ammonia from ammonium salts by an acid–base reaction