(a) describe van der Waals’ forces as the intermolecular forces between molecular entities other than those due to bond formation, and use the term van der Waals’ forces as a generic term to describe all intermolecular forces (b) describe the types of van der Waals’ forces: • instantaneous dipole–induced dipole (id-id) forces, also called London dispersion forces • permanent dipole–permanent dipole (pd-pd) forces, including hydrogen bonding (c) describe hydrogen bonding and understand that hydrogen bonding is a special case of permanent dipole–permanent dipole forces between molecules where hydrogen is bonded to a highly electronegative atom
describe addition polymerisation as exemplified by poly(ethene) and poly(chloroethene), PVC
(a) describe covalent bonds in terms of orbital overlap giving σ and π bonds: - σ bonds are formed by direct overlap of orbitals between the bonding atoms - π bonds are formed by the sideways overlap of adjacent p orbitals above and below the σ bond (b) describe how the σ and π bonds form in molecules including H\(_2\), C\(_2\)H\(_6\), C\(_2\)H\(_4\), HCN and N\(_2\) (c) use the concept of hybridisation to describe sp, sp\(^2\) and sp\(^3\) orbitals