(a) describe hydrogen bonding, limited to molecules containing N–H and O–H groups, including ammonia and water as simple examples (b) use the concept of hydrogen bonding to explain the anomalous properties of H\(_2\)O (ice and water): • its relatively high melting and boiling points • its relatively high surface tension • the density of the solid ice compared with the liquid water
describe the following reactions of alkenes: (a) the electrophilic addition of (i) hydrogen in a hydrogenation reaction, \( H_2(g) \) and Pt/Ni catalyst and heat (ii) steam, \( H_2O(g) \) and \( H_3PO_4 \) catalyst (iii) a hydrogen halide, \( HX(g) \), at room temperature (iv) a halogen, \( X_2 \) (b) the oxidation by cold dilute acidified \( KMnO_4 \) to form the diol (c) the oxidation by hot concentrated acidified \( KMnO_4 \) leading to the rupture of the carbon–carbon double bond and the identities of the subsequent products to determine the position of alkene linkages in larger molecules (d) addition polymerisation exemplified by the reactions of ethene and propene
describe, in simple terms, the lattice structure of a crystalline solid which is: (a) giant ionic, including sodium chloride and magnesium oxide (b) simple molecular, including iodine, buckminsterfullerene \( C_{60} \) and ice (c) giant molecular, including silicon(IV) oxide, graphite and diamond (d) giant metallic, including copper